Page 3 - HA
P. 3

(37)Describe the change in hybridisation (if any) of the Al atom in the

               following reaction .
                                -
                                         -
                       AlCl  +Cl  →AlCl 4
                          3
               (38)Is there any change in the hybridisation of B and N atoms as a result
               of the following reaction ?



                                                        BF + NH → F  B.NH 3
                                                        3
                                                               3
                                                3
               (39)Which hybrid orbitals are used by carbon atoms in the following
               molecules ?CH3-CH3; (b) CH3-CH=CH2; (c) CH3-CH2-OH; (d) CH3-CHO


               (e) CH3COOH


                                                                    +
               (40)What is the hybridisation of N in NH ?
                                                                   4
               (41) What is the hybridisation of P in PCl ?
                                                                    5
               (42)What is the bond order of O ?
                                                         2

               (43)What is the magnetic character of N ?
                                                                    2

               (44)What is the magnetic character of super oxide ion  of oxygen ?


               (45)In between N  and O  whose bond order is more ?
                                      2
                                                2
               (46)Arrange the following according to their bond strength :


                                 -
                                       2-
                            +
                      O , O ,O , O
                                      2
                           2
                       2
                                2
               (48)Use molecular orbital theory to explain why the Be2 molecule does
               not exist.
               (49)Compare the relative stability of the following species and indicate
               their magnetic properties;

                                         2-
                                    -
                              +
                      O , O ,O , O
                             2
                       2
                                  2
                                        2
               (50)Write the significance of a plus and a minus sign shown in
               representing the orbitals.
   1   2   3   4